Spectroscopic and biological activity studies on tridentate schiff base ligands and their transition metal complexes. Synthesis and characterization of copper ii, nickel ii, and cobalt. Zabin2, manel jammali1 department of chemistr y, faculty of. The chemistry of metal complexes with schiff base ligands and their application have aroused considerable attention. Four heterocyclic rutheniumiii tridentate schiff base complexes formulated as rulcl 2 h 2 o where l tridentate onn schiff base ligand were synthesized and characterized using spectroscopic and analytical techniques.
Pdf spectroscopic and biological activity studies on. The resultant compound, r 1 r 2 cnr 3 is called a schiff base, where r 1 is an aryl group, r 2 is a hydrogen atom and r 3 is either an alkyl or aryl group. Ternary transition metal complexes of tridentate ono schiff base. In textile polymer manufacturing, organocobalt complexes with tridentate schiff base act as initiator of emulsion polymerization and co polymerization of dienyl. Both metal centers have distorted tricapped trigonal prism geometry, with the schiff base acting as tridentate ligand. Synthesis, spectroscopic, biological activities and dft calculations of nickelii mixedligand complexes of tridentate schiff bases.
Nickelii, and cobaltii chelates with tridentate schiff base ligands derived from. In order to evaluate the effect of metal ions upon chelation, the schiff bases and their complexes have. Ternary transition metal complexes of tridentate ono. Synthesis, photophysical, thermal and crystallographic studies of 3. Synthesis and biological properties abstract several new complexes of a tridentate ons schiff base derived from the condensation of sbenzyldithiocarbazate with salicylaldehyde have been characterised by elemental analyses, molar conductivity measurements and by i. Four new schiff bases containing n and s heteroatoms hl1hl4 have been prepared and characterized, including determination of the xray crystal structures of hl1 and hl3.
Synthesis, characterization, and biological activity of. A novel method was developed for synthesizing a series of new tri. The xray crystal structure of complex 8 shows distorted octahedral geometry of vanadium, with ono ligand in equatorial position. Environmentally benign studies of bivalent transition. Among the schiff base derivatives tested, 32pyridylethylimino2butanoneoxime, having one oxime and a pyridine. New complexes of niii and cuii with tridentate ono schiff base. Materials free fulltext copper tridentate schiff base.
Rutheniumiii complexes of heterocyclic tridentate onn. Microwave synthesis and spectral, thermal and antimicrobial activities of some novel transition metal complexes with tridentate schiff base ligands rajendra k. Synthesis, characterisation, and biological evaluation of. Spectroscopic evidence indicates that these schiff bases behave as uninegatively charged tridentate nns ligands in complexes of general formula culnsac ln is the anionic form of nns, and sac represents. The tridentate schiff base ligand forms six membered and fivemembered chelate rings at. We report the first use of bimetallic copper acetate complex 3 bearing nno tridentate schiff base ligands as an efficient catalyst for choco2 copolymerization in a controlled character, producing polymers with controllable molecular weights and a highly alternating microstructure up to 96% carbonate linkages. Binuclear tetrahedral dimeric mgii complexes of dibasic. Research article synthesis, characterisation, and biological evaluation of znii complex with tridentate nno donor schiff base ligand nayazahmed, 1 mohdriaz, 2 altafahmed, 3 andmadhulikabhagat 4 department of chemistry, sadhu vaswani college, bairagarh, bhopal, india. The ligand is yellow, nickel complex is pale green, manganese complex is grass green coloured while copper complex is light green. To examine the directivity for improving the silver ion discrimination ability of a schiff base, three kinds of tridentate ligands were synthesized and compared with the similar quadridentate ligand as the silver ionophore. New complexes of niii and cuii with tridentate ono schiff base ligand.
Doubly phenoxidebridged binuclear copperii complexes. Pdf dicopperii complexes of a tridentate pyrimidine. Nickleii complexes with schiff base obtained by the condensation of 1,3propaneamine with salicylaldehyde and thiosalicylaldehyde which present as n2os or n2s2 coordination sphere have been prepared and studied3. Niii, cuii, and znii complexes of tetradentate schiff base. Synthesis, antibacterial studies and crystal structures of tridentate schiff base ligand and its cobaltiii complex. Thiocyanate ligand was used in addition to coordinate to transition metal ion, which presents a novel in transition metal complex. Structural characterization, quantum chemical calculations and invitro antidiabetic activity. Dicopperii complexes of a tridentate pyrimidine derived schiff base ligand. Using this tridentate ligand, complex of znii with general formula ml has been synthesized. Ejidike and others published cuii complexes of tridentate schiff base ligand. Tridentate schiff base, orthoaminophenol, mgii complexes, antibacterial activity, dimeric tetrahedral geometry introduction a schiff base named after hugo schiff, is a compound that contains azomethine group cn connected to an aryl or alkyl group but not hydrogen. The microanalyses were in good agreement with the proposed structures of the compounds.
The ligand and the metalii complexes were isolated pure from etoh in good yields. Synthesis and characterization of ni ii complex with. Pdf the cobaltii complex of a new tridentate schiff. Synthesis and characterization of mixedligand copperii. Journal of chemical crystallography, aug 2012 mehdi salehi, grzegorz dutkiewicz, arezou rezaei, ali amoozadeh, salman rahmani, gholam hossein grivani, maciej kubicki. Additionally, a tetradentate schiff base ligand 3,4bis2hydroxy3 methoxyphenylmethyl eneaminophenylphenylmethanone l5 was synthesized. Schif f bases of thiodiazole have good plant growth regulator activity towards auxin and cytokin95. The compounds were characterized by elemental analysis, electronic and infrared spectroscopic techniques. Synthesis, characterization and antibacterial activity of.
Pdf synthesis, spectroscopic, biological activities and. Pdf in this research, we prepared a new series of the cuii 1 and niii 2 metal complexes of a tridentate schiff base ligand. Dioxidovanadiumv complexes of a tridentate ono schiff base ligand. Synthesis, characterization and antibacterial activity of a tridentate. They were reported to show diverse biological activity14 and have many applications as ligands in coordination chemistry of transition metals5,6. The schiff base honsh behaves as a dinegatively charged ligand coordinating through the thiolo sulphur, the azomethine nitrogen and the hydroxyl oxygen. Pdf cuii complexes of tridentate schiff base ligand. The biological properties were evaluated to determine.
Condensation of 1methyl2imidazolecarboxaldehyde with 21methylhydrazinylpyridine results in the synthesis of new, tridentate schiff base ligand l, which readily reacts with cocl 2 to form a monometallic colcl 2 complex that, upon reduction. Box 193953697, tehran, iran received 2 december 2015, revised 19 june, accepted 20 june 2016 abstract. All the ecofriendly synthesized schiff bases and their metal complexes were characterized by analytical and spectral methods. Lanthanideiii complexes with tridentate schiff base ligand, antioxidant activity and xray crystal structures of the ndiii and smiii complexes mbosse ndiaye gueyea, moussa dienga, ibrahima elhadji thiama, djiby loa, aliou hamady barryb, mohamed gayea, and pascal retailleauc adepartment of chemistry, university cheikh anta diop, dakar. Pdf new complexes of niii and cuii with tridentate ono schiff. Chelates of nickelii and copperii with tridentate schiff base formed by the condensation of sbenzyldithiocarbazate with benzoin. The synthesized schiff bases act as deprotonated tridentate for the complexation reaction with cu ii, ni ii and znii ions.
A good linear correlation was observed between the oxidation potentials and the electronwithdrawing. Besides salentype ligands, a tridentate schiff base ligand with 2quinoxalinol as backbone is also employed to the oxidation reaction. In situ transformation of a tridentate to a tetradentate unsymmetric. Tridentate schiff base chromiumiii complex 1 catalyzes the asymmetric heteroene reaction between aryl aldehydes and either 2methoxypropene or 2trimethylsilyloxypropene to provide a series of. Syntheses, crystal structures and catalytic reactions.
Preparation and characterization of schiff base cu ii complex and. Schiff bases are widely employed in synthetic organic and inorganic chemistry. Nine new vanadium complexes, with tridentate schiff base ligand based on 3,5ditertbutyl2hydroxybenzaldehyde and different hydrazides, are described and characterized. Synthesis, photophysical, thermal and crystallographic. Synthesis, spectroscopy, electrochemistry and thermal study of vanadyl tridentate schiff base complexes. Many organic ligands particularly tridentate schiff base ligands show enhanced antibacterial, antifungal, and carcinostatic activity when complexed to transition metal ions 17. Dioxidovanadiumv complexes of a tridentate ono schiff.
Uvvis spectroscopy and cyclic voltammetry are employed to study the electronic properties of such tridentate ligand bound cuii complex. Taking advantage of the coordinative behavior of a tridentate schiff. Environmentally benign studies of bivalent transition metal complexes of tridentate nno donor schiff base ligands k. Research article mononuclear transition metal chelates. Synthesis, characterization, and biological activity of nickelii complexes with a tridentate schiff base derived from heterocyclic aldehyde. Schiff bases by the 1hnmr spectra is concerned, a very small difference in the.
Cu 2 l 2 1 is obtained in 85% and 75% yield in the. Electrochemical properties of the vanadyl complexes were investigated by cyclic voltammetry. Electrochemistry, thermalanalysis, and theoretical study. Lanthanideiii complexes with tridentate schiff base ligand. Post graduate college ranikhet263645 uttarakhand india.
Mishra department of chemistry, synthetic inorganic and coordination chemistry laboratories, dr. The resulting species will carry out the oxidations of substrates. These complexes are mixedligand by the presence of an unsymmetrical nno type tridentate schiff base l, and a 2,2. Tetradentate schiff base ligands of 3,4diaminobenzophenone.
Metal complex of the schiff base was prepared from salt of niii on 1. The tridentate onodonor schiff base ligand h 2 l, derived from the condensation of 1anisyl1,3butanedione and 2aminophenol, was generated in situ and reacted with cuno 3 23h 2 o to yield two doubly phenoxo bridged dicopperii complexes depending on the nitrogenous base used. Synthesis, antibacterial studies and crystal structures of. These tridentate schiff bases formed complexes of the type ml2xz where m coll, cuii. Synthesis and antimicrobial studies of tridentate schiff. Unsymmetrical schiff base functionalized as monobasic tridentate ligand on complexation with some transition metal ions bibhesh k. The bivalent cu, ni and zn complexes of unsymmetrical ono tridentate schiff base ligands derived from 2aminobenzoic acid. Copper tridentate schiff base complex supported on sba15. Synthesis, spectroscopy, electrochemistry and thermal. Additionally, a tetradentate schiff base ligand 3,4bis2hydroxy3methoxyphenylmethyl eneaminophenylphenylmethanone l5 was synthesized. Economical oxygenation of olefins and sulfides catalyzed.
Enantioselective and regioselective friedelcrafts alkylation of pyrroles with nitroalkenes catalyzed by a tridentate schiff base copper complex. Developing metalbased drugs is emerging as an active area of research. Schiff base which coupled with transition and non transition metal ions to form large amount of complexes2. The present paper deals with the synthesis and characterization of metal complex of tridentate schiff base ligand derived from the inserted condensation of 2aminobenzimidazole 1hbenzimidazol2amine with salicylaldehyde 2hydroxybenzaldehyde in a 1.
Mixedligand copper complexes with unsymmetrical tridentate schiff. Mixedligand copper complexes with unsymmetrical tridentate schiff base ligands and 2,2. Synthesis, stoichiometric, spectral, thermogravimetric and. Other therapeutic activities several schiff bases possess antiinflammatory, allergic inhibitors reducing activity96 radical. Synthesis, characterization and biological evaluation of some transition metal complexes of tridentate ono donor schiff base derived from ovanillin and thiazole moiety. Role of tridentate schiff base and methoxyethylindenyl derivatives of lanthanocene complexes for the synthesis of high molecular weight polymethyl methacrylate pmma. The novel nanocatalysts exhibited a highly ordered mesostructure with a surface area of 346 m2g. The bivalent cu, ni and zn complexes of unsymmetrical ono. We have been using n2odonor schiff bases for quite some time to.
Lanthanideiii complexes with tridentate schiff base. The anchorage of a supported copper schiff base complex on sba15 materials provides highly efficient heterogeneous catalysts towards the solventfree synthesis of dihydropyrimidinones derivatives via the biginelli condensation reaction. The schiff base ligand hl behaves as a monoanionic tridentate nno chelating agent. College for women autonomous, vellore, india bdepartment of chemistry, chikkaiah naicker college, erode, india. Hefei national laboratory of physical sciences at the microscale, cas key laboratory of soft matter chemistry, joint laboratory of green synthetic chemistry and department of. The schiff base ligand is the monocondensed form of the reaction between meso1,2diphenyl1,2ethylenediamine with salicylaldehyde derivatives. The voiv complexes of tridentate ono schiff base ligands derived from 2 aminobenzoicacid and salicylaldehyde derivatives were synthesized and characterized by ir, uvvis and elemental analysis. Several new complexes of a tridentate ons schiff base derived from the condensation of sbenzyldithiocarbazate with salicylaldehyde have been characterised by elemental analyses, molar conductivity measurements and by i. Pdf tridentate hydrazidohydrazones vanadium complexes. Unsymmetrical schiff base functionalized as monobasic. Xray crystallographic analysis of a closely related chromium complex reveals a bridged, dimeric structure bearing aquobound six. New schiff bases have been synthesised by the condensation of.
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